Novel Z2 Topological Metals and Semimetals

© 2016 American Physical Society.We report two theoretical discoveries for Z2 topological metals and semimetals. It is shown first that any dimensional Z2 Fermi surface is topologically equivalent to a Fermi point. Then the famous conventional no-go theorem, which was merely proven before for Z Fermi points in a periodic system without any discrete symmetry, is generalized so that the total topological charge is zero for all cases. Most remarkably, we find and prove an unconventional strong no-go theorem: all Z2 Fermi points have the same topological charge νZ2=1 or 0 for periodic systems. Moreover, we also establish all six topological types of Z2 models for realistic physical dimensions.postprin

An Improved Differential Evolution Algorithm for Maritime Collision Avoidance Route Planning

High accuracy navigation and surveillance systems are pivotal to ensure efficient ship route planning and marine safety. Based on existing ship navigation and maritime collision prevention rules, an improved approach for collision avoidance route planning using a differential evolution algorithm was developed. Simulation results show that the algorithm is capable of significantly enhancing the optimized route over current methods. It has the potential to be used as a tool to generate optimal vessel routing in the presence of conflicts

Enhanced Coagulation of Titanium Tetrachloride Aided by the Modified Compound Bioflocculant

© 2015 American Society of Civil Engineers. The compound bioflocculant (CBF) was modified by graft copolymerization of acrylic amide and dimethyl diallyl ammonium chloride, and the novel copolymer was denoted as MCBF. The effect of MCBF used as coagulant aid with titanium tetrachloride (TiCl4) was investigated for both high and low molecule weight natural organic matter (NOM) removal. Floc characteristics were studied using a laser diffraction particle-sizing device. Results indicated that the monomers were successfully grafted onto the CBF, and the molecule weight and zeta potential of CBF were greatly improved. The MCBF with TiCl4 exhibited synergistic effect by promoting NOM removal, especially at low TiCl4 doses. Additionally, using MCBF as a coagulant aid with TiCl4 can significantly increase the floc growth rate, size, strength, and broken-floc recoverability. The effect of MCBF on fractal dimension of flocs generated by TiCl4 depended on NOM properties. Both coagulation performance and floc properties were significantly affected by dosing sequence

Coagulation performance and floc characteristics of polytitanium tetrachloride and titanium tetrachloride compared with ferric chloride for coal mining wastewater treatment

© 2015 Elsevier B.V. Abstract The production and discharge of large volumes of wastewater during coal mining activities are one of the major environmental issues in Australia. Therefore, it is crucial to develop and optimise effective treatment processes for the safe disposal of coal mining wastewater (CMWW). In this study, we investigated the performance of a recently developed polytitanium tetrachloride (PTC) coagulant and compared with the performance of titanium tetrachloride (TiCl4) and the commonly used ferric chloride (FeCl3) coagulant for the treatment of CMWW from one of the coal mining sites in Australia. The use of Ti-based coagulants is particularly attractive for the CMWW treatment due to the advantage of being able to recycle the sludge to produce functional titanium dioxide (TiO2) photocatalyst; unlike the flocs formed using conventional coagulants, which need to be disposed in landfill sites. The results showed that both PTC and TiCl4 performed better than FeCl3 in terms of turbidity, UV254 and inorganic compounds (e.g. aluminium, copper or zinc) removal, however, PTC performed poorly in terms of dissolved organic carbon removal (i.e. less than 10%). While charge neutralisation and bridging adsorption were the main coagulation mechanisms identified for TiCl4 treatment; sweep coagulation and bridging adsorption seemed to play a more important role for both PTC and FeCl3 treatments. The flocs formed by PTC coagulation achieved the largest floc size of around 900 μm with the highest floc growth rate. Both Ti-based coagulants (i.e., PTC and TiCl4) showed higher strength factor than FeCl3, while TiCl4 coagulant yielded the flocs with the highest recovery factor. This study indicates that Ti-based coagulants are effective and promising coagulants for the treatment of CMWW

Removal of natural organic matter by titanium tetrachloride: The effect of total hardness and ionic strength

This study is the first attempt to investigate the effect of total hardness and ionic strength on coagulation performance and the floc characteristics of titanium tetrachloride (TiCl4). Membrane fouling under different total hardness and ionic strength conditions was also evaluated during a coagulation-ultrafiltration (C-UF) hybrid process. Coagulation experiments were performed with two simulated waters, using humic acid (HA, high molecular weight) and fulvic acid (FA, relatively low molecular weight), respectively, as model natural organic matter (NOM). Results show that both particle and organic matter removal can be enhanced by increasing total hardness and ionic strength. Floc characteristics were significantly influenced by total hardness and ionic strength and were improved in terms of floc size, growth rate, strength, recoverability and compactness. The results of the UF tests show that the pre-coagulation with TiCl4 significantly improves the membrane permeate fluxes. Under different total hardness and ionic strength conditions, the membrane permeate flux varied according to both NOM and floc characteristics. The increase in total hardness and ionic strength improved the membrane permeate flux in the case of HA simulated water treatment. © 2014 Elsevier Ltd

An environmentally friendly solution-processed ZrLaO gate dielectric for large-area applications in the harsh radiation environment

In this work, an eco-friendly aqueous solution-processed ZrLaO dielectric is demonstrated for large-area application in the harsh radiation environment. Appropriate La doping (10% La) into ZrOx could suppress the formation of Vo and improve the InOx/ZrLaO interface. The Zr0.9La0.1Oy thin films remained stable under 144 krad (SiO2) gamma-ray irradiation, no distinct composition variation or property degradation were observed. The resistor-loaded inverter based on InOx/Zr0.9La0.1Oy TFT demonstrated full swing characteristics with a gain of 13.3 at 4 V and remained 91% gain after 103 krad (SiO2) irradiation